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Additions to and Substitutions at C-C ?-Bonds

Additions to and Substitutions at C-C ?-Bonds

M.F. Semmelhack

Pergamon
Publication date : 1992-09-08

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Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

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About the book

Author

M.F. Semmelhack

Imprint

Pergamon

Collection

n.c

Publication date

1992-09-08

Pages

1322 pages

Print ISBN

9780080405957

Language

English

Ebook informations

EAN PDF DRM-FREE

9780080912479

Price

£437.82

Informations accessibility

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About author(s)

M.F. Semmelhack

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